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蓝宇，2003年和2008年在北京大学完成获本科和博士学位，2009年至2012年在美国加州大学洛杉矶分校从事博士后研究。2012年加入 独立开展科学研究，历任特聘研究员、教授、博士生导师。现任理论与计算化学重庆市重点实验室主任。蓝宇工作聚焦反应机制调控下的功能分子精准合成。通过对合成反应进行理性设计，实现原理和机制指导的功能分子精准合成。在此领域，近年来以通讯作者（含共同）在包括Nature（1篇）、Nat. Chem.（2篇）、J. Am. Chem. Soc.（22篇）、Angew. Chem. Int. Ed.（30篇）、Nat. Commun.（12篇）、Acc. Chem. Res.（2篇）、Chem（4篇）等期刊上发表学术论文250余篇，累计被他人引用过万次。蓝宇入选“重庆市青年专家工作室”，入选中国青年化学家元素周期表（中国化学会）代言“钽”，入选中国化学会高级会员。蓝宇2018年获国家自然科学基金优秀青年基金资助，曾主持国家自然科学基金项目四项。蓝宇获2016年中国化学会青年化学奖，2018年重庆市自然科学奖一等奖（第一完成人），2018年重庆大学唐立新优秀科研教师奖二等奖。 |
联系方式
LanYu@cqu.edu.cn
研究方向
自由基偶联反应相关机制；
电环化反应机理与选择性；
过渡金属促进烃类官能团化反应机理；
小分子催化反应立体化学。
代表性论文、专著和专利
近期代表作：
专著
(4) “Computational Methods in Organometallic Catalysis” Lan, Y. WILEY-VCH GmbH, Germany, 2021. (ISBN: 978-3-527-34601-1)
(3) “Computational Phosphorus Chemistry” Lan, Y.; Zhang, H.; Wei, D. et al. Chemical Industry Press Co., Ltd., China, 2023. (ISBN: 978-7-122-42553-9)
(2) “Computational Advances of Rh-Catalyzed C–H Functionalization” Lan, Y.; Cui, C.-X.; Liu, S.; Li, C.-X.; Bai, R. Springer Nature, Singapore, 2021. (ISBN: 978-981-16-0431-7)
(1) “Ru-Catalyzed C-H Functionalization of Heterocycles. In Handbook of CH‐Functionalization” Bai, R.; Shan, C.; Lan, Y. WILEY-VCH GmbH, Germany, 2022. (DOI: 10.1002/9783527834242.chf0238)
论文
(302) “Ligand-Controlled Regiodivergent Ring Expansion of Benzosilacyclobutenes with Alkynes en Route to Axially Chiral Silacyclohexenyl Arenes” Tang,X.; Tang, Y.; Peng, J.; Du, H.; Huang, L.; Gao, J.; Liu, S.; Wang, D.; Wang, W.; Gao, L.; Lan, Y.* Song Z.* J. Am. Chem. Soc. 2024, ASAP. (DOI: 10.1021/jacs.4c00252)
(301) “Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C-H Functionalization” Wang, X.; He, J.; Wang, Y.-N.; Zhao, Z.; Jiang, K.; Yang, W.; Zhang, T.; Jia, S.*; Zhong, K.*; Niu, L.*; Lan, Y.* Chem. Rev. 2024, 124, 10192. (DOI: 10.1021/acs.chemrev.4c00188)
(300) “Asymmetric hydrogenation of ketimines with minimally different alkyl groups” Wang, M.; Liu, S.; Liu, H.; Wang, Y.; Lan, Y.*; Liu, Q.* Nat. 2024, 631, 556-562. (DOI: 10.1038/s41586-024-07581-z)
(299) “Mechanistic insights into facilitating reductive elimination from Ni(II) species” Qiao, B.; Lin, F.-Y.; Fu, D.; Li, S.-J.; Zhang, T.*; Lan, Y.* Chem. Commun. 2024, 60, 8008-8019. (DOI: 10.1039/d4cc02667e)
(298) “Alkene insertion enables ring-opening of vinyl epoxides: a theoretical perspective” Liu, J.; Yang, K.; Liu, J.; Fu, D.; Li, S.-J.*; Zhang, W.*; Lan, Y.* Org. Chem. Front. 2024, 11, 4730-4739. (DOI: 10.1039/d4qo00950a)
(297) “Visible-light-driven synthesis of N-heteroaromatic carboxylic acids by thiolate-catalysed carboxylation of C(sp²)-H bonds using CO2” Jiang, Y.-X.; Liao, L.-L.; Gao, T.-Y.; Xu, W.-H.; Zhang, W.; Song, L.; Sun, G.-Q.; Ye, J.-H.*; Lan, Y.*; Yu, D.-G.* Nat. Synth. 2024, 3, 394-405. (DOI: 10.1038/s44160-023-00465-6)
(296) “Enhancing Hydride Transfer in Catalytic Hydrogenation via σ‑Electron-Induced Polarization of Imines” Liu, S.; Yang, H.; Wang, Y.-N.; Zhao, Q.; Wang, Y.*; Bai, R.*; Liu, Q.*; Lan, Y.* J. Am. Chem. Soc. 2024, 146, 16357-16362. (DOI: 10.1021/jacs.4c02096)
(295) “Synthesis of benzooxepane-fused cyclobutene derivatives via Pd-catalyzed cascade reactions of haloarenes and diynylic ethers” Zhu, S.*; Huang, W.; Liu, S.; Yu, R.; Ma, Y.; Wang, H.; Zhang, R.; Liu, B.; Lan, Y.*; Shen, R. Chem. Commun. 2024, 60, 5707-5710. (DOI: 10.1039/d4cc00999a)
(294) “Bond Dissociation Energy-Controlled Regioselectivity in Hydrofunctionalization” Peng, J.; He, X.; Luo, X.; Zhong, K.*; Liao, L.-L.*; Bai, R.*; Lan, Y.* ACS Catal. 2024, 14, 8030-8040. (DOI: 10.1021/acscatal.4c00304)
(293) “Chemo-, regio- and stereoselective access to polysubstituted 1,3-dienes via Nickel-catalyzed four-component reactions” Chen, S.; Wang, Y.-N.; Xie, J.; Li, W.; Ye, M.; Ma, X.; Yang, K.; Li, S.; Lan, Y.*; Song, Q.* Nat. Commun. 2024, 15, 5479. (DOI: 10.1038/s41467-024-49870-1)
(292) “Making Full Use of TMSCF3: Deoxygenative Trifluoromethylation/Silylation of Amides” Wang, Y.; Li, S.-J.; Jiang, F.; Lan, Y.*; Wang, X.* J. Am. Chem. Soc. 2024, 146, 19286-19294. (DOI: 10.1021/jacs.4c04760)
(291) “Copper- and Palladium-Cocatalyzed Chemo‑, Regio‑, Stereo‑, and Atroposelective Arylboration of 1,3-Enynes” Li, W.; Chen, H.; Zheng, Y.; Lu, Y.; Xie, J.; Chen, S.; Lan, Y.*; Song ,Q.* ACS Catal. 2024, 14, 11318-11331. (DOI: 10.1021/acscatal.4c03301)
(290) “Iron photocatalysis via Brønsted acid-unlocked ligand-to-metal charge transfer” Jiang, X.; Lan, Y.*; Hao, Y.; Jiang, K.; He, J.; Zhu, J.; Jia, S.; Song, J.; Li, S.-J.*; Niu, L.* Nat. Commun. 2024, 15, 6115. (DOI: 10.1038/s41467-024-50507-6)
(289) “Rhodium-Catalyzed Direct ortho-Arylation of Anilines” Jacob, C.; Annibaletto, J.; Peng, J.; Bai, R.; Maes, B. U. W.; Lan, Y.*; Evano, G.* Angew. Chem. Int. Ed. 2024, 63, e202403553. (DOI: 10.1002/anie.202403553)
(288) “Metal-Free 1,3-Boronate Rearrangement to Ketones Driven by Visible Light” Hao, K.; Li, D.; Fu, D.; Zou, P.; Xie, S.; Lan, Y.*; Chen, Y.* Angew. Chem. Int. Ed. 2024, 63, e202316481. (DOI: 10.1002/anie.202316481)
(287) “Enantio- and regioselective [2 + 2 + 2] cycloaddition of BN-diynes for construction of C-B axial chirality” Wang, H.; Qiao, B.; Zhu, J.; Guo, H.; Zhang, Z.; Yang, K.*; Li, S.-J.; Lan, Y.*; Song, Q.* Chem 2024, 10, 317-329. (DOI: 10.1016/j.chempr.2023.09.017)
(286) “Well-defined chiral dinuclear copper complexes in enantioselective propargylic substitution: For a long-standing supposition on binuclear mechanism” Cai, Q.; Rao, H.; Li, S.-J.; Lan, Y.*; Ding, K.*; Wang, X.* Chem 2024, 10, 265-282. (DOI: 10.1016/j.chempr.2023.09.006)
(285) “Transition-metal-free C(sp2)–C(sp3) cross-coupling of α-(pseudo)halo aliphatic ketones with boronic acids via a 1,4-metallate shift” Li, X.; Chen, H.; Wang, H.; Zhang, Q.; Sheng, H.; Lan, Y.*; Song, Q.* Nat. Synth. 2023, 2, 1211-1221. (DOI: 10.1038/s44160-023-00373-9)
(284) “Theoretical Study of How Electronic Effect of Substituent Affects Regioselectivity of C—Si Reductive Elimination” Peng, J.; He, X.; Liao, L.-L.*; Bai, R.*; Lan, Y.* Chin. J. Org. Chem. 2023, 43, 3608-3613. (DOI: 10.6023/cjoc202308009)
(283) “Axial chirality reversal and enantioselective access to Si-stereogenic silylallene” Jin, C.; He, X.; Chen, S.; Guo, Z.; Lan, Y.*; Shen, X.* Chem 2023, 9, 2956-2970. (DOI: 10.1016/j.chempr.2023.06.014)
(282) “Anion-Tuning of Organozincs Steering Cobalt-Catalyzed Radical Relay Couplings” Liu, X.; Chen, H.; Yang, D.; Hu, B.; Hu, Y.; Wang, S.; Lan, Y.*; Lei, A.*; Li, J.* ACS Catal. 2023, 13, 9254-9263. (DOI: 10.1021/acscatal.3c01022)
(281) “Origins of Catalyst-Controlled Chemoselectivity in Transition-Metal-Catalyzed Divergent Epoxide Conversion” Wang, X.; Yang, K.; Wang, Y.-N.; Li, S.-J.*; Wei, D.*; Lan, Y.* ACS Catal. 2023, 13, 7616-7626. (DOI: 10.1021/acscatal.3c01022)
(280) “A bridged backbone strategy enables collective synthesis of strychnan alkaloids” Zhou, W.; Xi, S.; Chen, H.; Jiang, D.; Yang, J.; Liu, S.; He, L.; Qiu, H.; Lan, Y.*; Zhang, M.* Nat. Chem. 2023, 15, 1074-1082. (DOI: 10.1038/s41557-023-01264-4)
(279) “A theoretical study of selective radical relay and coupling reactions for alkene difunctionalization” Yang, K.; Liu, J.; Fu, D.; Niu, L.*; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2023, 10, 4336-4341. (DOI: 10.1039/d3qo00357d)
(278) “Oxidative cyclopalladation triggers the hydroalkylation of alkynes” Zhong, K.; Liu, S.; He, X.; Ni, H.; Lai, W.; Gong, W.; Shan, C.; Zhao, Z.; Lan, Y.*; Bai, R.* Chin. Chem. Lett. 2023, 34, 108339. (DOI: 10.1016/j.cclet.2023.108339)
(277) “Programmable zigzag π-extension toward graphene-like molecules by the stacking of naphthalene blocks” Yin, J.; Li, J.; Chen, H.; Wang, Y.; Zhang, Y.; Zhang, C.; Bin, Z.; Pyle, D.; Yang, Y.; Lan, Y.*; You, J.* Nat. Synth. 2023, 2, 838-847. (DOI: 10.1038/s44160-023-00306-6)
(276) “Visible-light-driven thio-carboxylation of alkynes with CO2: facile synthesis of thiochromones” Miao, M.; Zhu, L.; Zhao, H.; Song, L.; Yan, S.-S.; Liao, L.-L.; Ye, J.-H.*; Lan, Y.*; Yu, D.-G.* Sci. Chin. Chem. 2023, 66, 1457-1466. (DOI: 10.1007/s11426-022-1554-x)
(275) “Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2” Zhang, W.; Liao, L.-L.; Li, L.; Liu, Y.; Dai, L.-F.; Sun, G.-Q.; Ran, C.-K.; Ye, J.-H.*; Lan, Y.*; Yu, D.-G.* Angew. Chem. Int. Ed. 2023, 62, e202301892. (DOI: 10.1002/anie.202301892)
(274) “Catalytic asymmetric oxa-Diels–Alder reaction of acroleins with simple alkenes” Zeng, L.; Liu, S.; Lan, Y.*; Gao, L.* Nat. Commun. 2023, 14, 3511. (DOI: 10.1038/s41467-023-39184-z)
(273) “Palladium-Catalyzed Cross-Coupling, Divergent Allene Generation, and Cycloadditions toward Cyclobuta[b]naphthalen-3(1H)‑ones and 11H-Benzo[b]fluoren-11-ones” Zhu, S.*; Wang, D.; Liu, S.; Ma, Y.; Wang, H.; Lan, Y.*; Bai, R.; Shen, R.* ACS Catal. 2023, 13, 8402-8412. (DOI: 10.1021/acscatal.3c00857)
(272) “Deaminative radical reactions via relayed proton-coupled electron transfer” Shi, Q.; Chen, K.; Guo, L.; Han, L.; Wei, D.*; Lan, Y.* Org. Chem. Front. 2023, 10, 2155-2164. (DOI: 10.1039/d3qo00192j)
(271) “Counteranion-Directed Catalysis for Asymmetric Radical Cation Transformations” Bao, P.; Lan, Y.* Chin. J. Org. Chem. 2023, 43, 1600-1601. (DOI: 10.6023/cjoc202300021)
(270) “Regiodivergent catalytic asymmetric dearomative cycloaddition of bicyclic heteroaromatics” Peng, L.; Zeng, Z.; Li, K.; Liu, Y.; Lan, Y.*; Yan, H.* Sci. Adv. 2023, 9, eadg1645. (DOI: 10.1126/sciadv.adg1645)
(269) “Empowering boronic acids as hydroxyl synthons for aryne induced three-component coupling reactions” Fan, R.; Liu, S.; Yan, Q.; Wei, Y.; Wang, J.; Lan, Y.*; Tan, J.* Chem. Sci. 2023, 14, 4278-4287. (DOI: 10.1039/d3sc00072a)
(268) “UV light–driven late-stage skeletal reorganization to diverse limonoid frameworks: A proof of concept for photobiosynthesis” Wu, J.; Li, S.-J.; Jiang, L.; Ma, X.-C.*; Lan, Y.*; Shen, L.* Sci. Adv. 2023, 9, eade2981. (DOI: 10.1126/sciadv.ade2981)
(267) “Remote Stereocontrol of All-Carbon Quaternary Centers via Cobalt-Catalyzed Asymmetric Olefin Isomerization” Rong, X.; Yang, J.; Liu, S.; Lan, Y.*; Liu, Q.* CCS Chem. 2023, 5, 1293-1300. (DOI: 10.31635/ccschem.023.202202616)
(266) “Organocatalytic asymmetric deoxygenation of sulfones to access chiral sulfinyl compounds” Huang, S.; Zeng, Z.; Zhang, N.; Qin, W.*; Lan, Y.*; Yan, H.* Nat. Chem. 2023, 15, 185-193. (DOI: 10.1038/s41557-022-01120-x)
(265) “N‑Heterocyclic Carbene/Brønsted Acid Cooperatively Catalyzed Conversions of α, β‑Unsaturated Carbonyls: Hydrogen Bond Donor/Acceptor-Electrophile/Nucleophile Combination Models” Wang, X.; Wang, Y.-N.; Pei, Z.; Li, S.-J.; Wei, D.*; Lan, Y.* ACS Catal. 2023, 13, 612-623. (DOI: 10.1021/acscatal.2c05373)
(264) “Revised Mechanism of C(sp3)−C(sp3) Reductive Elimination from Ni(II) with the Assistance of a Z‑Type Metalloligand” Zhang, T.; Zhong, K.; Lin, Z.-K.; Niu, L.; Li, Z.-Q.; Bai, R.*; Engle, K. M.*; Lan, Y.* J. Am. Chem. Soc. 2023, 145, 2207-2218. (DOI: 10.1021/jacs.2c09739)
(263) “Formyl Radical Generation from α-Chloro N-Methoxyphthalimides Enables Selective Aldehyde Synthesis” Liu, D.; Yang, K.; Fang, D.; Li, S.-J.; Lan, Y.*; Chen, Y.* Angew. Chem. Int. Ed. 2023, 62, e202213686. (DOI: 10.1002/anie.202213686)
(262) “Mechanistic views and computational studies on transition-metal-catalyzed reductive coupling reactions” Duan, A.*; Xiao, F.; Lan, Y.*; Niu, L.* Chem. Soc. Rev. 2022, 51, 9986-10015. (DOI: 10.1039/d2cs00371f)
(261) “Triazole-phosphine Pd(II)-Enabled Dehydrogenation of Alcohols or Amines: A Combination of Experimental and Theoretical Study” Tian, Y.; Liu, Y.; Han, J.; Liu, L.; Luo, H.; Hou, M.; Bai, R.; Lan, Y.*; Li, B.* Organometallics 2022, 41, 3504-3513. (DOI: 10.1021/acs.organomet.2c00276)
(260) “Azoarene activation for Schmidt-type reaction and mechanistic insights” Meng, F.-T.; Wang, Y.-N.; Qin, X.-Y.; Li, S.-J.; Li, J.; Hao, W.-J.*; Tu, S.-J.; Lan, Y.*; Jiang, B.* Nat. Commun. 2022, 13, 7393. (DOI: 10.1038/s41467-022-35141-4)
(259) “Nickel-Catalyzed Cross-Redistribution between Hydrosilanes and Silacyclobutanes” Chen, S.; He, X.; Jin, C.; Zhang, W.; Yang, Y.; Liu, S.; Lan, Y.*; Houk, K. N.*; Shen, X.* Angew. Chem. Int. Ed. 2022, 61, e202213431. (DOI: 10.1002/anie.202213431)
(258) “Enantioselective Synthesis of Spirosilabicyclohexenes by Asymmetric Dual Ring Expansion of Spirosilabicyclobutane with Alkynes” Chen, H.; Peng, J.; Pang, Q.; Du, H.; Huang, L.; Gao, L.; Lan, Y.*; Yang, C.*; Song, Z.* Angew. Chem. Int. Ed. 2022, 61, e202212889. (DOI: 10.1002/anie. 202212889)
(257) “The in Vitro Biosynthesis of Chlorophyll b via Enzyme Catalysis” Niu, L.; Lan, Y.* ACS Cent. Sci. 2022, 8, 1373-1375. (DOI: 10.1021/acscentsci.2c00997)
(256) “Catalytic Multicomponent Synthesis of C-Acyl Glycosides by Consecutive Cross-Electrophile Couplings” Jiang, Y.; Yang, K.; Wei, Y.; Wang, Q.*; Li, S.-J.*; Lan, Y.*; Koh, M. J.* Angew. Chem. Int. Ed. 2022, 61, e202211043. (DOI: 10.1002/anie.202211043)
(255) “Structure, reactivity and catalytic properties of manganese-hydride amidate complexes” Wang, Y.; Liu, S.; Yang, H.; Li, H.; Lan, Y.*; Liu, Q.* Nat. Chem. 2022, 14, ASAP. (DOI: 10.1038/s41557-022-01036-6)
(254) “What is the difference between mono- and biphosphine ligands? Revealing the chemoselectivity in Pd-catalysed carbenation of bromonaphthalene” Gong, W.; Fu, D.; Zhong, K.; Ni, H.; He, X.; Shan, C.*; Li, R.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4916-4923. (DOI: 10.1039/d2qo00910b)
(253) “How Strain-Release Determines Chemoselectivity: A Mechanistic Study of Rhodium-Catalyzed Bicyclo[1.1.0]butane Activation” Lai, W.; Zhong, K.*; Liu, S.; Liu, S.; Chen, H.; Ni, H.; Zeng, Z.; Zhao, Z.; Lan, Y.*; Bai, R.* J. Phys. Chem. Lett. 2022, 13, 7694-7701. (DOI: 10.1021/acs.jpclett.2c01528)
(252) “Regio- and Stereoselective 1,2-Oxyhalogenation of Non-Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes” Liu, M.; Sun, J.; Zhang, T.; Ding, Y.; Han, Y.-Q.; Martín-Montero, R.; Lan, Y.*; Shi, B.-F.*; Engle, K. M.* Angew. Chem. Int. Ed. 2022, 61, e202209099. (DOI: 10.1002/anie.202209099)
(251) “Perfluoroarene Interaction-Controlled Chiral Phosphoric Acid-Catalyzed Enantioselective Michael Addition of Difluoroenoxysilanes to Azadienes: a Combination of Experimental and Theoretical Studies” Li, J.; Chen, H.; Zhong, R.; Zhu, L.; Liu, S.; Ding, H.; Yang, J.; Wang, L.; Lan, Y.*; Wang, Z.* ACS Catal. 2022, 12, 9655-9663. (DOI: 10.1021/acscatal.2c01671)
(250) “The chiral pyridoxal-catalyzed biomimetic Mannich reaction: the mechanism and origin of stereoselectivity” Han, L.-L.; Zhang, Q.-Y.; Li, X.; Qiao, Y.*; Lan, Y.*; Wei, D.* Org. Chem. Front. 2022, 9, 4401-4410. (DOI: 10.1039/d2qo00705c)
(249) “Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes” Chen, S.; He, X.; Jin, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2022, 13, 3691. (DOI: 10.1038/s41467-022-31458-2)
(248) “The regioselectivity of the sulfonylation of tetrazoles: a theoretical view” Liu, C.-C.; Qiao, B.; Qu, L.-B.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4009-4015. (DOI: 10.1039/d2qo00797e)
(247) “Iminyl radical-triggered relay annulation for the construction of bridged aza-tetracycles bearing four contiguous stereogenic centers” Jiang, K.; Li, S.-J.; Liu, Q.-P.; Yu, N.; Li, Y.-L.; Zhou, Y.-Q.; He, K.-C.; Lin, J.; Zheng, T.-Y.; Lang, J.; Lan, Y.*; Wei, Y.* Chem. Sci. 2022, 13, 7283-7288. (DOI: 10.1039/d2sc01548j)
(246) “An alternative non-redox Ni(I) pathway in hydroaminomethylation: A theoretical perspective” Qiao, B.; Bai, R.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Mol. Catal. 2022, 526, 112378. (DOI: 10.1016/j.mcat.2022.112378)
(245) “Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission” Tang, Q.; Li, S.-J.; Ye, X.; Yuan, T.; Zhao, K.; He, Y.; Shan, C.; Wojtas, L.; Richardson, D.; Lan, Y.*; Shi, X.* Chem. Sci. 2022, 13, 5982-5987. (DOI: 10.1039/d2sc01103d)
(244) “Visible-light-induced cross-coupling of aryl iodides with hydrazones via an EDA-complex” Pan, P.; Liu, S.; Lan, Y.*; Zeng, H.*; Li, C.-J.* Chem. Sci. 2022, 13, 7165-7171. (DOI: 10.1039/d2sc01909d)
(243) “NHC-Catalyzed Transformation Reactions of Imines: Electrophilic versus Nucleophilic Attack” Liu, C.; Han, P.; Zhang, X.; Qiao, Y.; Xu, Z.; Zhang, Y.; Li, D.; Wei, D.*; Lan, Y.* J. Org. Chem. 2022, 87, 7989-7994. (DOI: 10.1021/acs.joc.2c00621)
(242) “Enantioselective Nickel-Catalyzed Si−C(sp2) Bond Activation and Migratory Insertion to Aldehydes: Reaction Scope and Mechanism” Wang, Q.; Zhong, K.-B.; Xu, H.; Li, S.-N.; Zhu, W.-K.; Ye, F.; Xu, Z.; Lan, Y.*; Xu, L.-W.* ACS Catal. 2022, 12, 4571-4580. (DOI: 10.1021/acscatal.2c00533)
(241) “Palladium-Catalyzed Asymmetric [3 + 2] Annulation of Vinylethylene Carbonates with Alkenes Installed on Cyclic N‑Sulfonyl Imines: Highly Enantio- and Diastereoselective Construction of Chiral Tetrahydrofuran Scaffolds Bearing Three Vicinal and Quaternary Stereocenters” Ke, M.; Qiao, B.; Yu, Y.; Li, X.; Xiao, X.; Li, S.-J.; Lan, Y.*; Chen, F.* J. Org. Chem. 2022, 87, 5166-5177. (DOI: 10.1021/acs.joc.1c03157)
(240) “Boryl Radical Activation of Benzylic C−OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis” Li, W.-D.; Wu, Y.; Li, S.-J.; Jiang, Y.-Q.; Li, Y.-L.; Lan, Y.*; Xia, J.-B.* J. Am. Chem. Soc. 2022, 144, 8551-8559. (DOI: 10.1021/jacs.1c12463)
(239) “Theoretical study on mechanism of cycloaddition reaction between o-alkynylbenzaldoximes and hexynol catalyzed by silver(I)” Yang, X.; Hao, Q.; Li, S.*; Zhu, Y.*; Lan, Y.* Mol. Catal. 2022, 522, 112227. (DOI: 10.1016/j.mcat.2022.112227)
(238) “Regioselectivity of Pd-catalyzed o-carborane arylation: a theoretical view” Liu, J.; Fu, D.; Chen, Z.; Li, T.; Qu, L.-B.; Li, S.-J.*; Zhang, W.*; Lan, Y.* Org. Chem. Front. 2022, 9, 1686-1695. (DOI: 10.1039/d2qo00046f)
(237) “Regiospecific construction of m-alkenyl benzaldehyde from b-bromoenal and vinyl borate” Xin, X.; Liu, Y.; Zhong, L.; Li, Y.; Luo, H.; Liu, L.; Bai, R.; Lan, Y.*; Li, B.* Chem. Commun. 2022, 58, 4989-4992. (DOI: 10.1039/d2cc01441f)
(236) “The Stannum–Ene Reactions of Benzyne and Cyclohexyne with Superb Chemoselectivity for Cyclohexyne” Li, L.; Shan, C.; Shi, J.; Li, W.; Lan, Y.*; Li, Y.* Angew. Chem. Int. Ed. 2022, 61, e202117351. (DOI: 10.1002/anie.202117351)
(235) “Ligand-Controlled Site- and Enantioselective Carbene Insertion into Carbon-Silicon Bonds of Benzosilacyclobutanes” Huo, J.; Zhong, K.; Xue, Y.; Lyu, M.; Ping, Y.; Ouyang, W.; Liu, Z.; Lan, Y.*; Wang, J.* Chem. Eur. J. 2022, 28, e202200191. (DOI: 10.1002/chem.202200191)
(234) “Diradical Generation via Relayed Proton-Coupled Electron Transfer” Shi, Q.; Pei, Z.; Song, J.; Li, S.-J.; Wei, D.*; Coote, M. L.*; Lan, Y.* J. Am. Chem. Soc. 2022, 144, 3137-3145. (DOI: 10.1021/jacs.1c12360)
(233) “Mechanistic Investigation of Cu-Catalyzed Asymmetric Alkynylation of Cyclic N‑Sulfonyl Ketimines with Terminal Alkynes” Zeng, Z.; Yan, F.; Dai, M.; Yu, Z.; Liu, F.; Zhao, Z.; Bai, R.*; Lan, Y.* Organometallics 2022, 41, 270-277. (DOI: 10.1021/acs.organomet.1c00624)
(232) “Mechanistic investigation of zwitterionic MOF-catalyzed enyne annulation using UNLPF-14-MnIII as catalyst” Liu, T.; Duan, R.; Wang, Y.; Li, S.; Qu, L.; Song, J.*; Liu, Q.*; Lan, Y.* Chin. Chem. Lett. 2022, 33, 4281-4286. (DOI: 10.1016/j.cclet.2022.01.041)
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(154) “Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C−Si Bond Activation: A Theoretical Study” Liu, S.; Zhang, T.; Zhu, L.; Liu, F.; Bai, R.*; Lan, Y.* Org. Lett. 2020, 22, 2124-2128. (DOI: 10.1021/acs.orglett.9b04636)
(153) “Origin of Regio- and Stereoselectivity in the NHC-catalyzed Reaction of Alkyl Pyridinium with Aliphatic Enal” Wang, Y.; Qu, L.-B.; Lan, Y.*; Wei, D.* ChemCatChem 2020, 12, 1068-1074. (DOI: 10.1002/cctc.201901965)
(152) “Nucleophilicity versus Brønsted basicity controlled chemoselectivity: mechanistic insight into silver- or scandium-catalyzed diazo functionalization” Liu, F.; Zhu, L.; Zhang, T.; Zhong, K.; Xiong, Q.; Shen, B.; Liu, S.; Lan, Y.*; Bai, R.* ACS Catal. 2020, 10, 1256-1263. (DOI: 10.1021/acscatal.9b02040)
(151) “Reaction Scope and Mechanistic Insights of Nickel-Catalyzed Migratory Suzuki-Miyaura Cross-Coupling” Li, Y.; Luo, Y.; Peng, L.; Li, Y.; Zhao, B.; Wang, W.; Pang, H.; Deng, Y.; Bai, R.; Lan, Y.*; Yin, G.* Nat. Commun. 2020, 11, 147. (DOI: 10.1038/s41467-019-14016-1)
(150) “Mechanism and origin of diastereoselectivity of N-heterocyclic carbene-catalyzed cross-benzoin reaction: A DFT study” Wang, Y.; Lan, Y.* Chin. Chem. Lett. 2020, 31, 736-738. (DOI: 10.1016/j.cclet.2019.08.010)
(149) “Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp3)-H Bond Allylation” Zhang, J.; Liu, D.; Liu, S.; Ge, Y.; Lan, Y.*; Chen, Y.* iScience, 2020, 23, 100755. (DOI: 10.1016/j.isci.2019.100755)
(148) “Mechanism and Substituent Effects of Benzene Arylation via a Phenyl Cation Strategy: A Density Functional Theory Study” Li, X.; Sun, L.; Zhang, Q.; Li, S.; Wang, Y.; Wei, D.; Zhang, W.*; Lan, Y.* ChemCatChem 2019, 11, 5068-5076. (DOI: 10.1002/cctc.201901120)
(147) “Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2” Chen, X.-W.; Zhu, L.; Gui, Y.-Y.; Jing, K.; Jiang, Y.-X.; Bo, Z.-Y.; Lan, Y.*, Li, J.; Yu, D.-G.* J. Am. Chem. Soc. 2019, 141, 18825-18835. (DOI: 10.1021/jacs.9b09721)
(146) “Unveiling How Intramolecular Stacking Modes of Covalently Linked Dimers Dictate Photoswitching Properties” Lu, R.-Q.; Yan, X.-Y.; Zhu, L.; Yang, L.-L.; Qu, H.; Wang, X.-C.*; Luo, M.; Wang, Y.; Chen, R.; Wang, X.-Y.; Lan, Y.*; Pei, J.; Weng, W.; Xia, H.; Cao, X.-Y.* Nat. Commun. 2019, 10, 5480. (DOI: 10.1038/s41467-019-13428-3)
(145) “Enantiodivergence by Minimal Modification of an Acyclic Chiral Secondary Aminocatalyst” Dai, J.; Wang, Z.; Deng, Y.; Zhu, L.; Peng, F.; Lan, Y.*; Shao, Z.* Nat. Commun. 2019, 10, 5182. (DOI: 10.1038/s41467-019-13183-5)
(144) “Oxidative Addition Promoted C−C Bond Cleavage in Rh-Mediated Cyclopropenone Activation: A DFT Study” Luo, Y.; Shan, C.; Liu, S.; Zhang, T.; Zhu, L.; Zhong, K.; Bai, R.*; Lan, Y.* ACS Catal. 2019, 9, 10876-10886. (DOI: 10.1021/acscatal.9b03361)
(143) “Unmasking the Ligand Effect in Manganese-Catalyzed Hydrogenations: Mechanistic Insight and Catalytic Application” Wang, Y.; Zhu, L.; Shao, Z.; Li, G.; Lan, Y.*; Liu, Q.* J. Am. Chem. Soc. 2019, 141, 17337-17349. (DOI: 10.1021/jacs.9b09038)
(142) “Origin of Regiochemical Control in Rh(III)/Rh(V)-Catalyzed Reactions of Unsaturated Oximes and Alkenes to Form Pyrdines” Li, Y.; Chen, H.; Qu, L.-B.; Houk, K. N.*; Lan, Y.* ACS Catal. 2019, 9, 7154-7165. (DOI: 10.1021/acscatal.9b02085)
(141) “On the mechanism of palladium-catalyzed unsaturated bond transformation: A review of theoretical studies” Xiong, Q.; Chen, H.; Zhang, T.; Shan, C.; Bai, R.*; Lan, Y.* Asian J. Org. Chem. 2019, 8, 1194-1206. (DOI: 10.1002/ajoc.201900314)
(140) “Mechanism of Rhodium Catalyzed Desymmetrization by Hydroacylation: A DFT Study” Luo, X.; Peng, J.; Liu, S.; Zhong, K.; Zhang, T.; Chen, R.; Lan, Y.* Sci. Sin. Chem. 2019, 49, 1094-1103. (DOI: 10.1360/SSC-2019-0051)
(139) “Inverse Electron-Demand, Pd-Catalyzed Asymmetric [4+2] Cycloadditions Enabled by Chiral P,S-Ligand and Hydrogen Bonding” Wang, Y.-N.; Xiong, Q.; Lu, L.-Q.*; Zhang, Q.-L.; Wang, Y.; Lan, Y.*; Xiao, W.-J.* Angew. Chem. Int. Ed. 2019, 58, 11013-11017. (DOI: 10.1002/anie.201905993)
(138) “Revealing the Reduction Process of Cu(II) by Sodium Bis(trimethylsilyl)amide” Yang, D.; Yi, H.; Chen, H.; Qi, X.; Lan, Y.*; Pao, C.-W.; Lee, J.-F.; Zhang, H.; Chen, Y.-H.; Lei, A.* Faraday Discuss. 2019, 220, 105-112. (DOI: 10.1039/C9FD00034H)
(137) “Hydrogen-bond-induced chiral axis construction: theoretical study of cinchonine-thiourea-catalyzed enantioselective intramolecular cycloaddition” Shan, C.; Zhang, T.; Xiong, Q.; Yan, H.*; Bai, R.*; Lan, Y.* Chem. Asian J. 2019, 14, 2731-2736. (DOI: 10.1002/asia.201900624)
(136) “Geometry, stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds” Li, Y.; Chen, H.; Qu, L.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2019, 30, 2249-2253. (DOI: 10.1016/j.cclet.2019.06.001)
(135) “S8-Catalyzed Triple Cleavage of Bromodifluoro Compounds for the Assembly of N-containing Heterocycles” Deng, S.; Chen, H.; Ma, X.; Zhou, Y.; Yang, K.; Lan, Y.*; Song, Q.* Chem. Sci. 2019, 10, 6828-6833. (DOI: 10.1039/c9sc01333d)
(134) “Unravelling the Mechanism and Selectivity of the NHC-catalyzed Three-Membered Ring‐Opening/Fluorination of Epoxy Enals: A DFT Study” Wang, Y.; Qu, L.-B.; Lan, Y.*; Wei, D.* ChemCatChem 2019, 11, 2919-2925. (DOI: 10.1002/cctc.201900424)
(133) “Mechanism of Brønsted-Base-Mediated Borylation of Propynols: A DFT Study” Chen, H.; Zhang, T.; Shan, C.; Liu, S.; Song, Q.*; Bai, R.*; Lan, Y.* Org. Lett. 2019, 21, 4924-4928. (DOI: 10.1021/acs.orglett.9b01180)
(132) “Key Intermediate in Copper-Mediated Arene Trifluoromethylation [nBu4N][Cu(Ar)(CF3)3]: Synthesis, Characterization and C(sp2)-CF3 Reductive Elimination” Lu, Z.; Liu, H.; Liu, S.; Leng, X.; Lan, Y.*; Shen, Q.* Angew. Chem. Int. Ed. 2019, 58, 8510-8514. (DOI: 10.1002/anie.201904041)
(131) “Chemoselective asymmetric dearomative [3 + 2] cycloaddition reactions of purines with aminocyclopropanes” Hao, E.-J.; Fu, D.-D.; Wang, D.-C.; Zhang, T.; Qu, G.-R.; Li, G.-X.; Lan, Y.*; Guo, H.-M. Org. Chem. Front. 2019, 6, 863-867. (DOI: 10.1039/c9qo00039a)
(130) “Theoretical Study of the Addition of Cu–Carbenes to Acetylenes to Form Chiral Allenes” Zhong, K.; Shan, C.; Zhu, L.; Liu, S.; Zhang, T.; Liu, F.; Shen, B.; Lan, Y.*; Bai, R.* J. Am. Chem. Soc. 2019, 141, 5227-5280. (DOI: 10.1021/jacs.8b13055)
(129) “Enantioselective Synthesis of Biaryl Atropisomers via Pd‐Catalyzed C–H Olefination using Chiral Spiro Phosphoric Acid Ligands” Luo, J.; Zhang, T.; Wang, L.; Liao, G.; Yao, Q.-J.; Wu, Y.-J.; Zhan, B.-B.; Lan, Y.*; Lin, X.-F.*; Shi, B.-F.* Angew. Chem. Int. Ed. 2019, 58, 6708-6712. (DOI: 10.1002/anie.201902126)
(128) “Asymmetric Propargylic Radical Cyanation Enabled by Dual Organophotoredox and Copper Catalysis” Lu, F.-D.; Liu, D.; Zhu, L.; Lu, L.-Q.*; Yang, Q.; Zhou, Q.-Q.; Wei, Y.; Lan, Y.*; Xiao, W.-J.* J. Am. Chem. Soc. 2019, 141, 6167-6172. (DOI: 10.1021/jacs.9b02338)
(127) “Theoretical prediction on the reactivity of the Co-mediated intramolecular Pauson-Khand reaction for constructing bicyclo-skeletons in natural products” Zhu, L.; Wang, Z.; Liu, S.; Zhang, T.; Yang, Z.*; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2019, 30, 889-894. (DOI: 10.1016/j.cclet.2019.03.024)
(126) “Role of Alkaline-Earth Metal-Catalyst: A Theoretical Study of Pyridines Hydroboration” Li, Y.; Wu, M.; Chen, H.; Xu, D.; Qu, L.; Zhang, J.; Bai, R.*; Lan, Y.* Front. Chem. 2019, 7, 149. (DOI: 10.3389/fchem.2019.00149)
(125) “Chiral Phosphoric Acid Catalyzed Asymmetric C(sp3)–H Functionalization of Biomass-Derived 2,5-Dimethylfuran via Two Sequential Cope-Type Rearrangements” Xu, L.; Chen, H.; Liu, J.; Zhou, L.; Liu, Q.; Lan, Y.*; Xiao, J.* Org. Chem. Front. 2019, 6, 1162-1167. (DOI: 10.1039/C8QO01375F)
(124) “Frontier Molecular Orbital Adjusted C–H Cleavage and Oxidative Addition in Nickel Catalyzed Alkyl C–H Arylation: A Computational Study” Zhang, T.; Liu, S.; Zhu, L.; Liu, F.; Zhong, K.; Zhang, Y.; Bai, R.*; Lan, Y.* Commun. Chem. 2019, 2, 31. (DOI: 10.1038/s42004-019-0132-5)
(123) “Palladium-Catalyzed Enantioselective C–H Aminocarbonylation: Synthesis of Chiral Isoquinolinones” Han, H.; Zhang, T.; Yang, S.-D.; Lan, Y.*; Xia, J.-B.* Org. Lett. 2019, 21, 1749-1754. (DOI: 10.1021/acs.orglett.9b00315)
(122) “Theoretical Study of Ni-Catalyzed C−N Radical−Radical Cross-Coupling” Liu, S.; Qi, X.*; Bai, R.; Lan, Y.* J. Org. Chem. 2019, 84, 3321-3327. (DOI: 10.1021/acs.joc.8b03245)
(121) “Investigating the Mechanism of Palladium Catalyzed Radical Oxidative C(sp3)-H Carbonylation: A DFT Study” Xiong, Q.; Xu, D.; Shan, C.; Liu, S.; Luo, Y.; Liu, F.; Liu, S.; Lan, Y.*; Bai, R.* Chem. Asian J. 2019, 14, 655-661. (DOI: 10.1002/asia.201801862)
(120) “Formal Asymmetric Cycloaddition of Activated α,β-Unsaturated Ketones with α-Diazomethylphosphonate Mediated by a Chiral Silver SPINOL Phosphate Catalyst” Zheng, B.; Chen, H.; Zhu, L.; Hou, X.; Wang, Y.; Lan, Y.*; Peng, Y.* Org. Lett. 2019, 21, 593-597. (DOI: 10.1021/acs.orglett.8b03436)
(119) “Mechanistic Insight into Palladium-Catalyzed Carbocyclization-Functionalization of Bisallene: A Computational Study” Zhang, J.; Shan, C.; Lv, K.; Zhu, L.; Li, Y.; Liu, T.*; Lan, Y.* ChemCatChem 2019, 11, 1228-1237. (DOI: 10.1002/cctc.201801934)
(118) “Kinetic Resolution of Allylic Alcohol with Chiral BINOL-based Alkoxides: A Combination of Experimental and Theoretical Studies” Liu, Y.; Liu, S.; Li, D.; Zhang, N.; Peng, L.; Ao, J.; Eui, C.; Lan, Y.*; Yan, H. J. Am. Chem. Soc. 2019, 141, 1150-1159. (DOI: 10.1021/jacs.8b12796)
(117) “Computational Advances Aiding Mechanistic Understanding of Silver-Catalyzed Carbene/Nitrene/Silylene Transfer Reactions” Zhang, J.; Shan, C.; Zhang, T.; Liu, T.*; Song, J.*; Lan, Y.* Coor. Chem. Rev. 2019, 382, 69-84. (DOI: 10.1016/j.ccr.2018.12.009)
(116) “Well-Designed Phosphine–Urea Ligand for Highly Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition of Methacrylonitrile: A Combined Experimental and Theoretical Study” Xiong, Y.; Du, Z.; Chen, H.; Yang, Z.; Tan, Q.; Zhang, C.; Zhu, L.; Lan, Y.*; Zhang, M.* J. Am. Chem. Soc. 2019, 141, 961-971. (DOI: 10.1021/jacs.8b10939)
(115) “Probing Enantioselectivity in Rhodium-Catalyzed Si-C Bond Cleavage to Construct Silicon-Stereocenter: A Theoretical Study” Yu, Z.; Zhang, T.; Bai, R.; Lan, Y.* Catal. Sci. Tech. 2019, 9, 646-651. (DOI: 10.1039/C8CY02261E)
(114) “On the Mechanism of Transition Metal-Catalyzed C-F Functionalization: Theoretical Advances” Li, Y.; Wang, Y.; Zhu, L.; Qu, L.; Lan, Y.* Chin. J. Org. Chem. 2019, 39, 38-46. (DOI: 10.6023/cjoc201810020)
(113) “Theoretical Advances of Transition Metals Mediated C―H Bonds Cleavage” Shan, C.*; Bai, R.; Lan, Y.* Acta Phys. -Chim. Sin. 2019, 35, 940-953. (DOI: 10.3866/PKU.WHXB201810052)
(112) “Gas molecule adsorption on twisted nanographene C96H36 derivative: A theoretical study” Cui, C.-X.*; Tian, Y.; Zhang, Y.-P.; Qu, L.-B.; Lan, Y.* Carbon 2019, 143, 385-390. (DOI: 10.1016/j.carbon.2018.11.030)
(111) “Benchmark Study of Popular Density Functionals for Calculating Binding Energies of Three-Center Two-Electron Bonds” Cui, C.-X.; Xu, D.; Ding, B.-W.; Qu, L.-B.; Zhang, Y.-P.*; Lan, Y.* J. Comput. Chem. 2019, 40, 657-670. (DOI: 10.1002/jcc.25752)
(110) “Photoredox Catalysis Modulated Nickel-Catalyzed Divergent Difunctionalization of Ethylene” Li, J.; Luo, Y.; Cheo, H. W.; Lan, Y.*; Wu, J.* Chem 2019, 5, 192-203. (DOI: 10.1016/j.chempr.2018.10.006)
(109) “Mechanistic Insights into Manganese(I)-Catalyzed Chemoselective Hydroarylations of Alkynes: A Theoretical Study” Wang, Z.; Zhu, L.; Zhong, K.; Qu, L.-B.; Bai, R.*; Lan, Y.* ChemCatChem 2018, 10, 5820-5826. (DOI: 10.1002/cctc.201801301)
(108) “Retro-metal-ene versus retro-Aldol: Mechanistic insight into Rh-catalysed formal [3+2] cycloaddition” Liu, S.; Zhang, T.; Zhu, L.; Zhong, K.; Gong, J.; Yang, Z.*; Bai, R.*; Lan, Y.* Chem. Commun. 2018, 13551-13554. (DOI: 10.1039/C8CC08335E)
(107) “Difluoromethylated Organogold(III) Complex cis-[Au(PCy3)(4-F-C6H4)(CF2H)(Cl)]: Preparation, Characterization and its C(sp2)−CF2H Reductive Elimination” Liu, S.; Kang, K.; Liu, S.; Wang, D.; Wei, P.*; Lan, Y.*; Shen, Q.* Organometallics 2018, 36, 3901-3908. (DOI: 10.1021/acs.organomet.8b00579)
(106) “Long Distance Unconjugated Agostic-Assisted 1,5-H Shift in a Rumediated Alder-Ene Type Reaction: Mechanism and Stereoselectivity” Shan, C.; Zhong, K.; Qi, X.; Xu, D.; Qu, L.-B.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 3178-3185. (DOI: 10.1039/C8QO00699G)
(105) “Base-catalyzed Borylation/B-O Elimination of Propynols and B2pin2 Delivering Tetrasubstituted Alkenylboronates” Kuang, Z.; Chen, H.; Yan, J.; Yang, K.; Lan, Y.*; Song, Q.* Org. Lett. 2018, 29, 5153-5157. (DOI: 10.1021/acs.orglett.8b02077)
(104) “Mechanistic View of Ru-Catalyzed C–H Bond Activation and Functionalization: Computational Advances” Shan, C.; Zhu, L.; Qu, L.-B.; Bai, R.*; Lan, Y.* Chem. Soc. Rev. 2018, 47, 7552-7576. (DOI: 10.1039/c8cs00036k)
(103) “Toward a Predictive Understandings of Phosphine-Catalyzed [3+2] Annulation of Allenoates with Acrylate or Imine” Yu, Z.; Jin, Z.; Duan, M.; Bai, R.*; Lu, Y.*; Lan, Y.* J. Org. Chem. 2018, 83, 9729-9740. (DOI: 10.1021/acs.joc.8b01259)
(102) “One-pot synthesis of β-lactams by the Ugi and Michael addition cascade reaction” Gao, X.; Shan, C.; Chen, Z.; Liu, Y.; Zhao, X.; Zhang, A.; Yu, P.; Galons, H.*; Lan, Y.*; Lu, K.* Org. Biomol. Chem. 2018, 16, 6096-6105. (DOI: 10.1039/c8ob01176a)
(101) “Editorial: Introduction to the special column on organocatalysis” Lan, Y.*; Liu, X.* Chin. Chem. Lett. 2018, 29, 1179-1180. (DOI: 10.1016/j.cclet.2018.07.009)
(100) “Experimental and Theoretical Studies on Ru(II)-Catalyzed Oxidative C−H/C−H Coupling of Phenols with Aromatic Amides Using Air as Oxidant: Scope, Synthetic Applications and Mechanistic Insights” Zhang, L.; Zhu, L.; Zhang, Y.; Yang, Y.; Wu, Y.; Ma, W.; Lan, Y.*; You, J.* ACS Catal. 2018, 8, 8324-8335. (DOI: 10.1021/acscatal.8b02816)
(99) “C6-Selective Direct Arylation of 2-Phenylpyridine via an Activated N-methylpyridinium Salt: A Combined Experimental and Theoretical Study” Yin, C.; Zhong, K.; Li, W.; Yang, X.; Sun, R.; Zhang, C.; Zheng, X.; Yuan, M.; Li, R.; Lan, Y.*; Fu, H.*; Chen, H.* Adv. Synth. Catal. 2018, 360, 3990-3998. (DOI: 10.1002/adsc.201800666)
(98) “Mechanism investigation for anoin-assisted nickel catalyzed C–F bond functionalization reaction: a DFT study” Zeng, Z.; Zhang, T.; Yue, X.; Zhang, H.*; Bai, R.*; Lan, Y.* Sci. Sin. Chem. 2018, 48, 736-742. (DOI: 10.1360/N032018-00105)
(97) “Catalytic Lactonization of Unactivated Aryl C−H Bonds with CO2: Experimental and Computational Investigation” Song, L.; Zhu, L.; Zhang, Z.; Ye, J.-H.; Yan, S.-S.; Han, J.-L.; Yin, Z.-B.; Lan, Y.*; Yu, D.-G.* Org. Lett. 2018, 20, 3776-3779.(DOI: 10.1021/acs.orglett.8b01363)
(96) “Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions” Li, Y.; Cheng, Y.; Shan, C.; Zhang, J.; Xu, D.; Bai, R.; Qu, L.; Lan, Y.* Chin. J. Org. Chem. 2018, 38, 1885-1896. (DOI: 10.6023/cjoc201804031)
(95) “Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2” Yan, S.-S.; Zhu, L.; Ye, J.-H.; Zhang, Z.; Huang, H.; Zeng, H.; Li, C.-J.*; Lan, Y.*; Yu, D.-G.* Chem. Sci. 2018, 9, 4873-4878. (DOI: 10.1039/c8sc01299g)
(94) “Author Profile” Lan, Yu* Angew. Chem. Int. Ed. 2018, 57, 11852. (DOI: 10.1002/anie.201804435)
(93) “Redox-Neutral Access to Isoquinolinones via Rhodium(III)-Catalyzed Annulations of O‑Pivaloyl Oximes with Ketenes” Yang, X.; Liu, S.; Yu, S.; Kong, L.; Lan, Y.*; Li, X.* Org. Lett. 2018, 20, 2698-2701. (DOI: 10.1021/acs.orglett.8b00906)
(92) “Ruthenium(II)-enabled para-selective C–H difluoromethylation of anilides and their derivatives” Yuan, C.; Zhu, L.; Chen, C.; Chen, X.; Yang, Y.; Lan, Y.*; Zhao, Y.* Nat. Commun. 2018, 9, 1189. (DOI: 10.1038/s41467-018-03341-6)
(91) “Aryne Trifunctionalization Enabled by 3-Silylaryne as 1,2-Benzdiyne Equivalent” Lv, C.; Wan, C.; Liu, S.; Lan, Y.*; Li, Y.* Org. Lett. 2018, 20, 1919-1923. (DOI: 10.1021/acs.orglett.8b00469)
(90) “Counterion Effect and Directing Group Effect in Rh-Mediated C-H Bond Activation Processes: A Theoretical Study” Luo, Y.; Liu, S.; Xu, D.; Qu, L.-B.; Luo, X.*; Bai, R.*; Lan, Y.* J. Organomet. Chem. 2018, 862, 148-153. (DOI: 10.1016/j.jorganchem.2018.03.016)
(89) “Mechanistic Insight Into Cobalt-Catalyzed Stereodivergent Semihydrogenation of Alkynes: The Story of Selectivity Control” Qi, X.; Liu, X.; Qu, L.-B.; Liu, Q.*; Lan, Y.* J. Catal. 2018, 362, 25-34. (DOI: 10.1016/j.jcat.2018.03.016)
(88) “Theoretical insight into phosphoric acid-catalyzed asymmetric conjugate addition of indolizines to α,β-unsaturated ketones” Chen, H.; Zhu, L.; Zhong, K.; Yue, X.; Qu, L.-B.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2018, 29, 1237-1241. (DOI: 10.1016/j.cclet.2018.03.018)
(87) “Mechanism of phosphinecatalyzed allene coupling reactions: advances in theoretical investigations” Cui, C.-X.; Shan, C.; Zhang, Y.-P.; Chen, X.-L.; Qu, L.-B.*; Lan, Y.* Chem. Asian J. 2018, 13, 1076-1088. (DOI: 10.1002/asia.201800146)
(86) “Ni-Catalyzed C–F Bond Functionalization of Unactivated Aryl Fluorides and Corresponding Coupling with Oxazoles” Yin, Y.; Yue, X.; Zhong, Q.; Jiang, H.; Bai, R.*; Lan, Y.*; Zhang, H. Adv. Synth. Catal. 2018, 360, 1639-1643. (DOI: 10.1002/adsc.201701506)
(85) “C–H bond Cleavage Occurring on a Rh(V) Intermediate: a Theoretical Study of Rh-Catalyzed Arene Azidation” Liu, S.; Qi, X.; Qu, L.-B.; Bai, R.*; Lan, Y.* Catal. Sci. Tech. 2018, 8, 1645-1651. (DOI: 10.1039/c7cy02367g)
(84) “Regioselective Palladium-Catalyzed C‑H Bond Trifluoroethylation of Indoles: Exploration and Mechanistic Insight” Zhang, H.; Wang, H.-Y.; Luo, Y.; Chen, C.; Cao, Y.; Chen, P.; Guo, Y.-L.; Lan, Y.*; Liu, G.* ACS Catal. 2018, 8, 2173-2180. (DOI: 10.1021/acscatal.7b03220)
(83) “Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: CF3O- Palladation Initiated by Pd(IV)” Chen, C.; Luo, Y.; Fu, L.; Chen, P.; Lan, Y.*; Liu, G.* J. Am. Chem. Soc. 2018, 140, 1207-1210. (DOI: 10.1021/jacs.7b11470)
(82) “Insights of Disilylation and Distannation: Sequence Influence and Ligand/Steric Effect in Pd-Catalyzed Difunctionalization of Carbenes” Yue, X.; Shan, C.; Qi, X.; Luo, X.; Zhu, L.; Zhang, T.; Li, Y.; Li, Y.; Bai, R.*; Lan, Y.* Dalton Trans. 2018, 46, 1819-1826. (DOI: 10.1039/C7DT04084A)
(81) “Ruthenium(II)-catalyzed C-H Difluoromethylation of Ketoxime: Tuning the Regioselectivity from meta to para Position” Yuan, C.; Zhu, L.; Zeng, R.; Lan, Y.*; Zhao, Y.* Angew. Chem. Int. Ed. 2018, 57, 1277-1281. (DOI: 10.1002/anie.201711221)
(80) “On the Mechanism of Copper-Catalyzed Oxytrifluoromethylation of Allylamines with CO2: A Computational Study” Zhu, L.; Ye, J.-H.; Duan, M.; Qi, X.; Yu, D.-G.*; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 633-639. (DOI: 10.1039/C7QO00838D)
(79) “Ni(I)–Ni(III) vs Ni(II)–Ni(IV): Mechanistic Study of Ni-catalyzed Alkylation of Benzamides with Alkyl Halides” Li, Y.; Zou, L.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 615-622. (DOI: 10.1039/C7QO00850C)
(78) “C(sp2)-C(sp2) Reductive Elimination from Well-Defined Diarylgold(III) Complexes” Kang, K.; Liu, S.; Xu, T.; Wang, D.; Leng, X.; Bai, R.; Lan, Y.*; Shen, Q.* Organometallics 2017, 35, 4727-4740. (DOI: 10.1021/acs.organomet.7b00588)
(77) “Reactivity and regioselectivity in Diels–Alder reactions of anion encapsulated fullerenes” Cui, C.-X.; Zhang, Z.-P.; Zhu, L.; Qu, L.-B.; Zhang, Y.-P.; Lan, Y.* Phys. Chem. Chem. Phys. 2017, 42, 30393-30401. (DOI: 10.1039/C7CP06365B)
(76) “Mechanism of Rhodium-Catalyzed C−H Functionalization: Advances in Theoretical Investigation” Qi, X.; Li, Y.; Bai, R.; Lan, Y.* Acc. Chem. Res. 2017, 50, 2799-2808. (DOI: 10.1021/acs.accounts.7b00400)
(75) “Radical Trifluoromethylative Dearomatization of Indoles and Furans with CO2” Ye. J.-H.; Zhu, L.; Yan, S.-S.; Miao, M.; Zhang, X.-C.; Zhou, W.-J.; Li, J.; Lan, Y.*; Yu, D.-G.* ACS Catal. 2017, 7, 8324-8330. (DOI: 10.1021/acscatal.7b02533)
(74) “Rhodium/Copper Cocatalyzed Highly trans-Selective 1,2- Diheteroarylation of Alkynes with Azoles via C−H Addition/Oxidative Cross-Coupling: A Combined Experimental and Theoretical Study” Tan, G.; Zhu, L.; Liao, X.; Lan, Y.*; You, J.* J. Am. Chem. Soc. 2017, 139, 15724-15737. (DOI: 10.1021/jacs.7b07242)
(73) “Nine-Membered Benzofuran-Fused Heterocycles: Enantioselective Synthesis by Pd-Catalysis and Rearrangement via Transannular Bond Formation” Rong, Z.-Q.; Yang, L.-C.; Liu, S.; Yu, Z.; Wang, Y.-N.; Tan, Z. Y.; Huang, R.-Z.; Lan, Y.*; Zhao, Y.* J. Am. Chem. Soc. 2017, 139, 15304-15307. (DOI: 10.1021/jacs.7b09161)
(72) “Mechanistic Study on the Fluoride-induced Activation of Kobayashi Precursor: pseudo-SN2 Pathway via a PentaCoordinated Silicon ate-Complex” Liu, S.; Li, Y.*; Lan, Y.* Eur. J. Org. Chem. 2017, 42, 6349-6353. (DOI: 10.1002/ejoc.201701249)
(71) “Cp*CoIII-Catalyzed Branch-Selective Hydroarylation of Alkynes via C−H Activation: Efficient Access to α-gem-Vinylindoles” Zhou, X.; Luo, Y.; Kong, L.; Xu, Y.; Zheng, G.; Lan, Y.*; Li, X.* ACS Catal. 2017, 7, 7296-7304. (DOI: 10.1021/acscatal.7b02248)
(70) “Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study” Xu, D.; Shan, C.; Li, Y.; Qi, X.; Luo, X.*; Bai, R.*; Lan, Y.* Inorg. Chem. Front. 2017, 4, 1813. (DOI: 10.1039/c7qi00459a)
(69) “From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3+2] Cycloaddition” Duan, M.; Zhu, L.; Qi, X.; Yu, Z.; Li, Y.; Bai, R.*; Lan, Y.* Sci. Rep. 2017, 7, 7619. ( DOI:10.1038/s41598-017-07863-9)
(68) “Catalyst-controlled regioselectivity in phosphine catalysis: the synthesis of spirocyclic benzofuranones via regiodivergent [3+2] annulations of aurones and an allenoate” Ni, H.; Yu, Z.; Yao, W.; Lan, Y.*; Ullah, N.*; Lu, Y.* Chem. Sci. 2017, 8, 5699-5704. (DOI: 10.1039/c7sc02176c)
(67) “Mechanistic insights into copper-catalyzed trifluoromethylation of aryl boronic acids: a theretical study.” He, X.; Shan, C.; Qi, X.*; Bai, R.*; Lan, Y.* Sci. Sin. Chem. 2017, 47, 859-864. (DOI: 10.1360/N032017-00056)
(66) “Ir(III)/Ir(V) or Ir(I)/Ir(III) Catalytic Cycle? Steric-Effect-Controlled Mechanism for the para-C−H Borylation of Arenes” Zhu, L.; Qi, X.; Li, Y.; Duan, M.; Zou, L.; Bai, R.*; Lan, Y.* Organometallics 2017, 36, 2107-2115. (DOI: 10.1021/acs.organomet.7b00151)
(65) “Chiral phosphine-mediated intramolecular [3+2] annulation: enhanced enantioselectivity by achiral Brønsted acid” Yao, W.; Yu, Z.; Wen, S.; Ni, H.; Ullah, N.*; Lan, Y.*; Lu, Y.* Chem. Sci. 2017, 8, 5196-5200. (DOI: 10.1039/c7sc00952f)
(64) “Enantioselective alkynylation of N-sulfonyl -ketiminoesters via a Friedel–Crafts alkylation strategy” Liu, R.-R.; Zhu, L.; Hu, J.-P.; Lu, C.-J.; Gao, J.-R.; Lan, Y.*; Jia, Y.-X.* Chem. Commun. 2017, 52, 5890-5893. (DOI: 10.1039/c7cc01015j)
(63) “Bioinspired Total Synthesis of Homodimericin A” Huang, J.; Gu, Y.; Guo, K.; Zhu, L.; Lan, Y.*; Gong, J.*; Yang, Z.* Angew. Chem. Int. Ed. 2017, 56, 7890-7894. ( DOI: 10.1002/anie.201702768)
(62) “Mechanism, Regio-, and Diastereoselectivity of Rh(III)-Catalyzed Cyclization Reactions of N‑Arylnitrones with Alkynes: A Density Functional Theory Study” Li, Y.; Shan, C.; Yang, Y.-F.; Shi, F.; Qi, X.; Houk, K. N.*; Lan, Y.* J. Phys. Chem. A 2017, 121, 4496-4504. ( DOI: 10.1021/acs.jpca.7b01020)
(61) “Bioinspired Asymmetric Synthesis of Hispidanin A” Li, F.; Tu, Q.; Chen, S.; Zhu, L.; Lan, Y.*; Gong, J.*; Yang, Z.* Angew. Chem. Int. Ed. 2017, 56, 5844-5848. (DOI: 0.1002/anie.201700838)
(60) “C−O Functionalization of α‑Oxyboronates: A Deoxygenative gemDiborylation and gem-Silylborylation of Aldehydes and Ketones” Wang, L.; Zhang, T.; Sun, W.; He, Z.; Xia, C.; Lan, Y.*; Liu, C.* J. Am. Chem. Soc. 2017, 139, 5257-5264. (DOI: 10.1021/jacs.7b02518)
(59) “Mononuclear or Dinuclear? Mechanistic Study of the ZincCatalyzed Oxidative Coupling of Aldehydes and Acetylenes” Yue, X.; Qi, X.; Bai, R.; Lei, A.*; Lan, Y.* Chem. Eur. J. 2017, 23, 6419-6425. (DOI: 10.1002/chem.201700733)
(58) “Mechanism of Alkaline Earth Metal Catalyzed Hydroboration of Carbodiimides: A Theoretical Study” Xu, D.; Shan, C.; Bai, R.*; Lan, Y.* Chin. J. Org. Chem. 2017, 37, 1231-1236. (DOI: 10.6023/cjoc201701033)
(57) “Regioselective -Addition of Deconjugated Butenolides: Enantioselective Synthesis of Dihydrocoumarins” Wu, B.; Yu, Z.; Gao, X.; Lan, Y.*; Zhou, Y.* Angew. Chem. Int. Ed. 2017, 56, 4006-4010. (DOI:10.1002/anie.201700437)
(56) “Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical–Radical Cross-Coupling” Qi, X.; Zhu, L.; Bai, R.*; Lan, Y.* Sci. Rep. 2017, 7, 43579. (DOI: 10.1038/srep43579)
(55) “Thiolate–palladium(IV) or sulfonium–palladate(0)? A theoretical study on the mechanism of palladium-catalyzed C–S bond formation reactions” Xu, D.; Qi, X.; Duan, M.; Yu, Z.; Zhu, L.; Shan, C.; Yue, X.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2017, 4, 943-950. (DOI: 10.1039/c6qo00841k)
(54) “Room-Temperature Coupling/Decarboxylation Reaction of α‑Oxocarboxylates with α‑Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones” He, Z.; Qi, X.; She, Z.; Zhao, Y.; Li, S.; Tang, J.; Gao, G.*; Lan, Y.*; You, J.* J. Org. Chem. 2017, 82, 1403-1411. (DOI: 10.1021/acs.joc.6b02575)
(53) “Application of Gausian Software in Organic Chemistry Teaching in Senior High School” Li, Y.;* Qi, X.; Lan, Y.* Chin. J. Chem. Edu. 2017, 38(13), 43. (DOI: 10.13884/J.1003-3807hxjy.2016120022)
(52) “Biomimetically inspired asymmetric total synthesis of (+)-19-dehydroxyl arisandilactone A” Han, Y.; Jiang, Y.; Li, Y.; Yu, H.; Tong, B.; Niu, Z.; Zhou, S.; Liu, S.; Lan, Y.;* Chen, J.;* Yang, Z.;* Nat. Commun. 2017, 8, 14233. (DOI: 10.1038/ncomms14233)
(51) “Ligand effect on nickle-catalyzed reductive alkyne-aldehyde coupling reactions: a computational study. ” Luo, X.; Li, Y.; Qi, X.; Zhu, L.; Chen, C.;* Lan, Y.* Sci. Sin. Chem. 2017, 47, 341-349. (DOI:10.1360/N032016-00129)
(50) “Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes” Zhang, T.; Qi, X.; Liu, S.; Bai, R.; * Liu, C.; * Lan, Y.* Chem.-Eur. J. 2017, 23, 2690-2699. (DOI: 10.1002/chem.201605188)
(49) “Readily Accessible and Highly Efficient Ferrocene-Based AminoPhosphine-Alcohol (f-Amphol) Ligands for Iridium-Catalyzed Asymmetric Hydrogenation of Simple Ketones” Yu, J.; Duan, M.; Wu, W.;Qi, X. ; Xue, P.; Lan, Y.;* Dong, X-Q.;* Zhang, X.;* Chem.-Eur. J. 2017, 23, 970-975. (DOI: 10.1002/chem.201604855)
(48) “C8–H bond activation vs. C2–H bond activation: from naphthyl amines to lactams” Shi, R.; Lu, L.; Xie, H.; Yan, J.; Xu, T.; Zhang, H.; Qi, X.; Lan, Y.*; Lei, A.* Chem. Commun. 2016, 52, 13307. (DOI: 10.1039/c6cc06358f)
(47) “Mild Acylation of C(sp3)−H and C(sp2)−H Bonds under Redox-Neutral Rh(III) Catalysis” Yu, S.; Li, Y.; Kong, L.; Zhou, X.; Tang, G.; Lan, Y.;* Li, X.* ACS Catal. 2016, 6, 7744-7748. (DOI: 10.1021/acscatal.6b02668)
(46) “Effective Chirality Transfer in [3+2] Reaction between AllenylRhodium and Enal: Mechanistic Study Based on DFT Calculations” Qi, X.; Liu, S.; Zhang, T.; Long, R.; Huang, J.; Gong, J.; Yang, Z.;* Lan, Y.* J. Org. Chem. 2016, 81, 8306-8311. (DOI: 10.1021/acs.joc.6b01429)
(45) “Asymmetric Transfer Hydrogenation of Imines using Alcohol: Efficiency and Selectivity are Influenced by the Hydrogen Donor” Pan, H. J.; Zhang, Y.; Shan, C.; Yu, Z.; Lan, Y.;* Zhao, Y.* Angew. Chem. Int. Ed. 2016, 55, 9615-9619. (DOI:10.1002/anie.201604025)
(44) “Reactivity of Single-Walled Carbon Nanotubes in the Diels–Alder Cycloaddition Reaction: Distortion–Interaction Analysis along the Reaction Pathway” Li, Y.; Osuna, S.; Garcia-Borràs, M.; Qi, X.; Liu, S.; Houk, K. N.;* Lan, Y.* Chem.-Eur. J. 2016, 22, 12819-12824. (DOI: 10.1002/chem.201601799)
(43) “Iridium Catalysts with f‑Amphox Ligands: Asymmetric Hydrogenation of Simple Ketones” Wu, W.; Liu, S.; Duan, M.; Tan, X.; Chen, C.; Xie, Y.; Lan, Y.;* Dong, X.-Q.; Zhang, X.* Org. Lett. 2016, 18, 2938-2941. (DOI: 10.1021/acs.orglett.6b01290)
(42) “Computational Studies on an Aminomethylation Precursor: (Xantphos)Pd(CH2NBn2)+” Qi, X.; Liu, S.; Lan, Y.* Organometallics 2016, 35, 1582-1585. (DOI: 10.1021/acs.organomet.6b00234)
(41) “Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp3)-H and C(sp2)-H under Rhodium(III) Catalysis” Yu, S.; Tang, G.; Li, Y.; Zhou, X.; Lan, Y.;* Li, X.* Angew. Chem. Int. Ed. 2016, 55, 8696-8700. (DOI: 10.1002/anie.201602224)
(40) “Efficient Synthesis of Dimeric Oxazoles, Piperidines and Tetrahydroisoquinolines from N-Substituted 2-Oxazolones” He, Y.;* Agarwal, P. K.; Kiran, I. N.; Yu, R.; Cao, B.; Zou, C.; Zhou, X.; Xu, H.; Xu, B.; Zhu, L.; Lan, Y.;* Nicolaou, K. C.* Chem.-Eur. J. 2016, 22, 7696-7701. (DOI: 10.1002/chem.201601471)
(39) “Regio- and Stereoselective Syntheses of 7-Oxabicyclo[2.2.1]heptanes via a Gold(I)-Catalyzed Cycloisomerization of Alkynediols: Asymmetric Total Synthesis of Farnesiferol C” Gu, Y.-Q.; Zhang, P.-P.; Fu, J.-K.; Liu, S.; Lan, Y.*; Gong, J.-X.*; Yang, Z.* Adv. Synth. Catal. 2016, 358, 1392-1397. (DOI: 10.1002/adsc.201600218)
(38) “Mechanism of Ruthenium-Catalyzed Direct Arylation of C−H Bonds in Aromatic Amides: A Computational Study” Shan, C.; Luo, X.; Qi, X.; Liu, S.; Li, Y.; Lan, Y.* Organometallics 2016, 35, 1440-1445. (DOI: 10.1021/acs.organomet.6b00064)
(37) “Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C−H Bond Activation” Gao, B.; Liu, S.; Lan, Y.*; Huang, H.* Organometallics 2016, 35, 1480-1487. (DOI: 10.1021/acs.organomet.6b00072)
(36) “Mechanism of Rhodium-Catalyzed Formyl Activation: A Computational Study” Luo, X.; Bai, R.; Liu, S.; Shan, C.; Chen, C.; Lan, Y.* J. Org. Chem. 2016, 81, 2320-2326. (DOI: 10.1021/acs.joc.5b02828)
(35) “Mechanism and electronic effect for the synthesis of 6-aroylated phenanthridines: a theoretical study” Xu, T.; Qi, X.; Lan, Y.* Sci. Sin. Chem. 2016, 46, 616-622. (DOI: 10.1360/N032015-00217)
(34) “Rhodium-Catalyzed Hetero-(5+2) Cycloaddition of Vinylaziridines and Alkynes: A Theoretical View of the Mechanism and Chirality Transfer” Zhu, L.; Qi, X.; Lan, Y.* Organometallics 2016, 35, 771-777. (DOI: 10.1021/acs.organomet.6b00007)
(33) “Rhodium(III)-Catalyzed Annulation between N‑Sulfinyl Ketoimines and Activated Olefins: C−H Activation Assisted by an Oxidizing N−S Bond” Wang, Q.; Li, Y.; Qi, Z.; Xie, F.; Lan, Y.*; Li, X.* ACS Catal. 2016, 6, 1971-1980. (DOI: 10.1021/acscatal.5b02297)
(32) “Gold(I)-Catalyzed Angle Strain Controlled Strategy to Furopyran Derivatives from Propargyl Vinyl Ethers: Insight into the Regioselectivity of Cycloisomerization” Jin, S.; Jiang, C.; Peng, X.; Shan, C.; Cui, S.; Niu, Y.; Liu, Y.; Lan, Y.*; Liu, Y.*; Cheng, M.* Org. Lett. 2016, 18, 680-683. (DOI: 10.1021/acs.orglett.5b03641)
(31) “Mechanism of Synergistic Cu(II)/Cu(I)-Mediated Alkyne Coupling: Dinuclear 1,2-Reductive Elimination after Minimum Energy Crossing Point” Qi, X.; Bai, R.; Zhu, L.; Jin, R.; Lei, A.; Lan, Y.* J. Org. Chem. 2016, 81, 1654-1660. (DOI: 10.1021/acs.joc.5b02797)
(30) “Iron-Catalyzed Decarboxylative (4+1) Cycloadditions: Exploiting the Reactivity of Ambident Iron-Stabilized Intermediates” Wang, Q.; Qi, X.; Lu, L. Q.*; Li, T. R.; Yuan, Z. G.; Zhang, K.; Li, B. J.; Lan, Y.*; Xiao, W. J.* Angew. Chem. Int. Ed. 2016, 55, 2840-2844. (DOI: 10.1002/anie.201510413)
(29) “Regiodivergent Enantioselective γ‑Additions of Oxazolones to 2,3-Butadienoates Catalyzed by Phosphines: Synthesis of α,α-Disubstituted α‑Amino Acids and N,O‑Acetal Derivatives” Wang, T.; Yu, Z.; Hoon, D. L.; Phee, C. Y.; Lan, Y.*; Lu, Y.* J. Am. Chem. Soc. 2016, 138, 265-271. (DOI: 10.1021/jacs.5b10524)
(28) “Mechanism, chemoselectivity and enantioselectivity for the rhodium-catalyzed desymmetric synthesis of hydrobenzofurans: a theoretical study” Yu, Z.; Qi, X.; Li, Y.; Liu, S.; Lan, Y.* Org. Chem. Front. 2016, 3, 209-216. (DOI: 10.1039/c5qo00334b)
(27) “Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine” Wu, K.; Huang, Z.; Qi, X.; Li, Y.; Zhang, G.; Liu, C.; Yi, H.; Meng, L.; Bunel, E. E.; Miller, J. T.; Pao, C. W.; Lee, J. F.; Lan, Y.*; Lei, A.* Sci. Adv. 2015, 1, e1500656. (DOI: 10.1126/sciadv.1500656)
(26) “Silver Migration Facilitates Isocyanide-Alkyne [3+2] Cycloaddition Reactions: Combined Experimental and Theoretical Study” Qi, X.; Zhang, H.; Shao, A.; Zhu, L.; Xu, T.; Gao, M.*; Liu, C.*; Lan, Y.* ACS Catal. 2015, 5, 6640-6647. ( DOI: 10.1021/acscatal.5b02009)
(25) “Towards a general diastereoselective route to oxabicyclo[3.2.1]octanes via a gold-catalysed cascade reaction” Fu, J.; Gu, Y.; Yuan, H.; Luo, T.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Nat. Commun. 2015, 6, 8617. (DOI: 10.1038/ncomms9617)
(24) “Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)-H Oxygenation” Lin, Y.; Zhu, L.; Lan, Y.*; Rao, Y.* Chem.-Eur. J. 2015, 21, 14937-14942. (DOI: 10.1002/chem.201502140.)
(23) “Diastereoselective Synthesis of Cyclopentanoids: Applications to the Construction of the ABCD Tetracyclic Core of Retigeranic Acid” A Zhang, J.; Wang, X.; Li, S.; Li, D.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Chem.-Eur. J. 2015, 21, 12596-12600. (DOI: 10.1002/chem.201502423)
(22) “Distortion–interaction analysis along the reaction pathway to reveal the reactivity of the Alder-ene reaction of enes” Jin, R.; Liu, S.; Lan, Y.* RSC Adv. 2015, 5, 61426-61435. (DOI: 10.1039/c5ra10345b)
(21) “Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings” Wang, T.; Yu, Z.; Hoon, D. L.; Huang, K.-W.; Lan, Y.*; Lu, Y.* Chem. Sci. 2015, 6, 4912-4922. (DOI: 10.1039/c5sc01614b)
(20) “Mechanism and selectivity for zinc-mediated cycloaddition of azides with alkynes: a computational study” Li, Y.; Qi, X.; Lei, Y.; Lan, Y.* RSC Adv. 2015, 5, 49802-49808. (DOI: 10.1039/c5ra02703a)
(19) “The Mechanism of N-O Bond Cleavage in Rhodium-Catalyzed C-H Bond Functionalization of Quinoline N-oxides with Alkynes:A Computational Study” Li, Y.; Liu, S.; Qi, Z.; Qi, X.; Li, X.*; Lan, Y.* Chem.-Eur. J. 2015, 21, 10131-10137. (DOI: 10.1002/chem.201500290)
(18) “Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study” Qi, X.; Li, Y.; Zhang, G.; Li, Y.; Lei, A.*; Liu, C.*; Lan, Y.* Dalton Trans. 2015, 44, 11165-11171. (DOI: 10.1039/c5dt01366f)
(17) “Tuning radical reactivity using iodine in oxidative C(sp3)–H/C(sp)–H cross-coupling: an easy way toward the synthesis of furans and indolizines” Tang, S.; Liu, K.; Long, Y.; Qi, X.; Lan, Y.*; Lei, A.* Chem. Commun. 2015, 51, 8769-8772. (DOI: 10.1039/c5cc01825k)
(16) “Nickel-Catalyzed Selective Oxidative Radical Cross-Coupling: An Effective Strategy for Inert Csp3−H Functionalization” Liu, D.; Li, Y.; Qi, X.; Liu, C.; Lan, Y.*; Lei, A.* Org. Lett. 2015, 17, 998-1001. (DOI: 10.1021/acs.orglett.5b00104)
(15) “Bimetallic zinc complex–active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation” Yuan, J.; Wang, J.; Zhang, G.; Liu, C.; Qi, X.; Lan, Y.*; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A.* Chem. Commun. 2015, 51, 576-579. (DOI: 10.1039/c4cc08152h)
(14) “Revealing the halide effect on the kinetics of the aerobic oxidation of Cu(I) to Cu(II)” Deng, Y.; Zhang, G.; Qi, X.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.*; Lei, A.* Chem. Commun. 2015, 51, 318-321. (DOI: 10.1039/c4cc05720a)
(13) “Transition-Metal-Free Formal Decarboxylative Coupling of a-Oxocarboxylates with a-Bromoketones under Neutral Conditions: A Simple Access to 1,3-Diketones” He, Z.; Qi, X.; Li, S.; Zhao, Y.; Gao, G.*; Lan, Y.*; Wu, Y.; Lan, J.; You, J.* Angew. Chem. Int. Ed. 2015, 54, 855-859. (DOI: 10.1002/anie.201409361)
(12) “Rhodium-Catalyzed C−H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C−N Bond: A Combination of Experimental and Theoretical Studies” Yu, S.; Liu, S.; Lan, Y.*; Wan, B.*; Li, X.* J. Am. Chem. Soc. 2015, 137, 1623-1631. (DOI: 10.1021/ja511796h)
(11) “Transition-Metal-Assisted Radical/Radical Cross-Coupling: A New Strategy to the Oxidative C(sp3)−H/N−H Cross-Coupling” Zhou, L.; Tang, S.; Qi, X.; Lin, C.; Liu, K.; Liu, C.; Lan, Y.*; Lei, A.* Org. Lett. 2014, 16, 3404-3407. (DOI: 10.1021/ol501485f)
(10) “Carbon-Centered Radical Addition to O=C of Amides or Esters as a Route to CO Bond Formations” Liu, D.; Tang, S.; Yi, H.; Liu, C.; Qi, X.; Lan, Y.*; Lei, A.* Chem.-Eur. J. 2014, 20, 15605-15610. (DOI: 10.1002/chem.201404607)
(9) “Chemoselective Carbophilic Addition of a-Diazoesters through Ligand-Controlled Gold Catalysis” Xi, Y.; Su, Y.; Yu, Z.; Dong, B.; McClain, E. J.; Lan, Y.*; Shi, X.* Angew. Chem. Int. Ed. 2014, 53, 9817-9821. (DOI: 10.1002/anie.201404946)
(8) “Visible-Light-Mediated Decarboxylation/Oxidative Amidation of α-Keto Acids with Amines under Mild Reaction Conditions Using O2” Liu, J.; Liu, Q.; Yi, H.; Qin, C.; Bai, R.; Qi, X.; Lan, Y.*; Lei, A.* Angew. Chem. Int. Ed. 2014, 53, 502-506. (DOI: 10.1002/anie.201308614)
(7) “Cu(II)−Cu(I) Synergistic Cooperation to Lead the Alkyne C−H Activation” Bai, R.; Zhang, G.; Yi, H.; Huang, Z.; Qi, X.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.*; Lei, A.* J. Am. Chem. Soc. 2014, 136, 16760-16763. (DOI: 10.1021/ja5097489)
(6) “Asymmetric total synthesis of (-)-lingzhiol via a Rh-catalysed [3+2] cycloaddition” Long, R.; Huang, J.; Shao, W.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Nat. Commun. 2014, 5, 5707. (DOI: 10.1038/ncomms6707)
(5) “Theoretical study of the electron-donating effects of thiourea ligands in catalysis” Liu, S.; Lei, Y.; Yang, Z.*; Lan, Y.* J. Mol. Struct. 2014, 1074, 527-533. (DOI:10.1016/j.molstruc.2014.06.034)
(4) “Hexahapto-chromium complexes of graphene: a theoretical study” Liu, S.; Lei, Y.; Li, Y.; Zhang, T.; Wang, H.; Lan, Y.* RSC Adv. 2014, 4, 28640. (DOI: 10.1039/c4ra03702b)
(3) “What Controls Stereoselectivity and Reactivity in the Synthesis of a trans-Decalin with a Quaternary Chiral Center via the Intramolecular Pauson−Khand Reaction: A Theoretical Study” Liu, S.; Shen, H.; Yu, Z.; Shi, L.; Yang, Z.*; Lan, Y.* Organometallics 2014, 33, 6282-6285. (DOI: 10.1021/om500840q )
(2) “Reactivity for the Diels−Alder Reaction of Cumulenes: A Distortion-Interaction Analysis along the Reaction Pathway” Liu, S.; Lei, Y.; Qi, X.; Lan, Y.* J. Phys. Chem. A 2014, 118, 2638-2645. (DOI: 10.1021/jp411914u)
(1) “Mechanism of Rhodium-Catalyzed Carbon−Silicon Bond Cleavage for the Synthesis of Benzosilole Derivatives: A Computational Study” Yu, Z.; Lan, Y.* J. Org. Chem. 2013, 78, 11501-11507. (DOI: 10.1021/jo402070f)
